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My experience is that socks won't smell if the feet are fungus free. You can use various foot powders to get the feet fungus free initially, such as boric acid, miconazole, clotrimazole, undecylate. Desenex uses undecylate and seems to work well, but most of my experience is with boric acid, which has worked like a charm on every foot fungus I've ever had. Once the feet are fungus free, you can keep them fungus free by walking barefoot an hour a day and exposing the feet to sunshine during rest stops.
Last summer, I wore various socks including at least two pairs of wool socks for three weeks straight each and nylon socks for several days straight (I used these after the second pair of wool socks until I could find a store selling more wool socks) without ever washing them with soap and usually only rinsing them every week or so and they never smelled, nor did my feet or shoes. The trick was that I kept fungus from growing on my feet.
If the feet are fungus free, then they don't smell, any more than fungus-free hands smell. When was the last time you washed your gloves or mittens? I've been wearing the same pair of fleece mittens all this winter without washing them and they certainly don't stink.
A few times last summer I had to walk all day with wet feet. Warm and wet is perfect conditions for breeding fungus. To prevent this, I sprinkled some boric acid in my shoes at the end of each of these rainy days.
I make a point of smelling my feet each morning while stretching to ensure they aren't getting fungus infected. Foot fungus is not just a problem with socks and shoes. It is also a great way to really stink up a sleeping bag like you wouldn't believe. You might think the smell would be confined to the foot area of the bag, but recall that you stuff the bag in a sack each day and so the smell can migrate to the rest of the bag. (I'm speaking form experience here, incidentally, from a trip of several years ago.) If that sleeping bag happens to be down, then good luck trying to get the stink out, unless you want to use bleach and hot water to clean it. I ended up just tossing my bag in the dumpster.
In the past, before I learned how to avoid foot fungus, I tried x-static socks and they only work slightly better than regular nylon/polypro liner socks at keeping smell down. X-static may prevent fungus from growing on the socks themselves, but it won't prevent the stink of fungus on the feet from being transferred to the socks (or shoes or sleeping bag). So the key is make the feet fungus-free.
As for t-shirts, I recommend you try very loose fitting pure supplex nylon instead of x-static. Just be sure to avoid that polyester "wicking" crap in the upper back area. Supplex is smell-resistant and can usually be cleaned by simply rinsing in cold water, such as in a stream. Whereas polyester typically requires hot water and detergent or even bleach to remove underarm smells. The same applies to shorts. Pure supplex shorts are highly resistant to urine smell, whereas with polyester shorts you start to stink like an incontinent homeless person after a few days and then it takes hot water and bleach to get things cleaned up again.
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