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rusty, spray paint should work very well, I used to be surprised how well it stuck to material, clothing, etc. Not perfect, but try a sample piece, get some fluorescent spray paint and give a test piece a spray to see how it works. My guess is it will work very well, even spraying cotton used to work well for me, not great, since it was so absorbent, but quite well.
With tyvek, which is just a plastic of sorts, I'd think it would stick really well, and wouldn't flake off too badly either, if at all.
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