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I would think using two inflatable mold surfaces would make it very difficult to make a part. Also, don't tires have a rough inside? That would have to be made very smooth, and a coating would have to be applied to help the part release from it when it's done curing. Now if a half pipe were used, an inner tube could still probably used with a film beneath it to help it release, although I think laying the CF over the pipe would be easier. Still though, how intricate is this fender going to be? Is it simply a fraction of the outer half of a torus, or will it include things like brackets or any other complex curves? If it's going to be complex, I'd say to make it out of foam carved with a hot wire, "paint" it with something that won't melt with the epoxy/resin being used, lay up the carbon fiber and cure it, and then melt the foam out.
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