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Allison, The alcohol & water both evaporate thru the cask which is known as the "angel's share". I would assume that many factors such as the porosity of the white oak casks, the surface tension of water molecules, the amount of air in the cask after fluids evaporate, the relative differences in the volatility of ethanol vs. H2O, the size of the cask (which varies greatly), & possibly even what the cask was previously filled with (American whiskey, sherry, port,rum, etc.)would all have an effect. Suffice it to say that I haven't a clue as to why the water would evaporate in greater concentration than the ethanol! I think I'll have a wee dram of 12 YO Macallan & think about this for a while! ;)
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