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The lowdown on annealing titanium can be found here: http://www.key-to-metals.com/Article97.htm If you look at the temps involved in the table at the bottom, you can see there's not much to worry about at small woodfire temps. In any case, the effect of heating and cooling titanium is generally to make it more ductile, so it shouldn't become more brittle, as long as you let it cool slowly rather than chucking a pan of water on it. Even if you had to do that in an emergency, it wouldn't affect it much, and a subsequent firing would re-anneal it anyway.
However, direct flame for extended periods can be a problem, although I would say a coat of wood tar on the inner surface should sufficiently protect the titanium:
http://www.azom.com/details.asp?ArticleID=1245 "Most titanium grades are typically stress-relieved at about 1000°F (538°C) for 45 minutes and annealed at 1300°F (704°C) for two hours. A slightly higher stress relief temperature [1100°F (593°C), 2 hrs.] and annealing temperature [1450°F (788°C), 4 hrs.] are appropriate for the Grade 5 alloy. Air cooling is generally acceptable.
Although no special furnace equipment or protective atmosphere is required for titanium, a slightly oxidizing atmosphere is recommended to prevent pickup of hydrogen. Direct flame impingement for extended periods, leading to temperatures in excess of 1200°F (649°C), should be avoided because of the potential for contamination and embrittlement."
You could consider a thin throwaway steel liner made from a food can if it becomes a problem... If you are going to try to roll-form it, a full annealing prior to working it would help. It's not very ductile stuff though, I think it'll be the very devil to create flanges etc on. Your duodeconal form may be the way to go. Alternatively, you could roll and rivet the tubes and joint them with a U section pressed ring.
How do I get my hands on some of this 0.005" sheet Steven? :-)
Edited by tallbloke on 07/24/2008 03:12:21 MDT.
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